H2N2V1, Main, Exploration, bibRecord, 000F80

1‐Amino‐2‐fluoromonocarba‐closo‐dodecaborates: K[1‐H2N‐2‐F‐closo‐1‐CB11H10] and [Et4N][1‐H2N‐2‐F‐closo‐1‐CB11I10]

Identifieur interne : 000F80 ( Main/Exploration ); précédent : 000F79; suivant : 000F81

1‐Amino‐2‐fluoromonocarba‐closo‐dodecaborates: K[1‐H2N‐2‐F‐closo‐1‐CB11H10] and [Et4N][1‐H2N‐2‐F‐closo‐1‐CB11I10]

Auteurs : Maik Finze [Allemagne] ; Jan A. P. Sprenger [Allemagne]

Source :

ZAAC ‐ Journal of Inorganic and General Chemistry [ 0044-2313 ] ; 2010-08.

RBID : ISTEX:F2853509853803EA5D27D087FB723AD7E82FCB88

English descriptors

Teeft :
- Acta crystallogr, Anion, Aqueous phase, Bond lengths, Boron, Boron atoms, Calcd, Chem, Chemical shifts, Crystal structure, Dalton trans, Diethyl ether, Disordered fluorine atom, Elemental analysis, Ether, Ethereal layer, Experimental section, Finze, Fluorine, Fluorine substituents, Hydrogen atoms, Independent reflections, Insertion reaction, Interatomic distances, Minor occupancies, Mmol, Monoclinic space group, Raman spectra, Raman spectroscopy, Reaction mixture, Residual ether, Room temperature, Rotary evaporator, Shielding constants, Solid residue, Verlag gmbh.

Abstract

The potassium salt of the [1‐H2N‐2‐F‐closo‐1‐CB11H10]– anion (1) was obtained from an insertion reaction of Li3[7‐H2N‐nido‐7‐CB10H10] with BF3·OEt2. Anion 1 was protonated to the neutral species 1‐H3N‐2‐F‐closo‐1‐CB11H10 (H1) and it was iodinated with ICl to the [1‐H2N‐2‐F‐closo‐1‐CB11I10]– anion (2). All species were characterized by multinuclear NMR, IR, and Raman spectroscopy as well as by elemental analysis. The structure of H1·(CH3)2CO was studied by single‐crystal X‐ray diffraction and the experimentally determined bond lengths are compared to values derived from density functional calculations.

Url:

https://api.istex.fr/ark:/67375/WNG-4FZN2R0X-7/fulltext.pdf

DOI: 10.1002/zaac.201000096

Affiliations:

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Le document en format XML

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<term>Boron atoms</term>
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<term>Chem</term>
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<term>Crystal structure</term>
<term>Dalton trans</term>
<term>Diethyl ether</term>
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<term>Finze</term>
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<front><div type="abstract" xml:lang="en">The potassium salt of the [1‐H2N‐2‐F‐closo‐1‐CB11H10]– anion (1) was obtained from an insertion reaction of Li3[7‐H2N‐nido‐7‐CB10H10] with BF3·OEt2. Anion 1 was protonated to the neutral species 1‐H3N‐2‐F‐closo‐1‐CB11H10 (H1) and it was iodinated with ICl to the [1‐H2N‐2‐F‐closo‐1‐CB11I10]– anion (2). All species were characterized by multinuclear NMR, IR, and Raman spectroscopy as well as by elemental analysis. The structure of H1·(CH3)2CO was studied by single‐crystal X‐ray diffraction and the experimentally determined bond lengths are compared to values derived from density functional calculations.</div>
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1‐Amino‐2‐fluoromonocarba‐closo‐dodecaborates: K[1‐H2N‐2‐F‐closo‐1‐CB11H10] and [Et4N][1‐H2N‐2‐F‐closo‐1‐CB11I10]

1‐Amino‐2‐fluoromonocarba‐closo‐dodecaborates: K[1‐H2N‐2‐F‐closo‐1‐CB11H10] and [Et4N][1‐H2N‐2‐F‐closo‐1‐CB11I10]

Source :

English descriptors

Abstract

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